Defined Intercalation Stages from Cathodic Reduction of MOS2 in Organic Electrolytes
نویسنده
چکیده
Cathodic reduction of M0S2 in DMSO electrolytes containing alkali cations A+ results in the formation of defined ternary phases A+o.i25 (DMSO)y[MoS2] 1 2 5 _ with highly mobile solvated interlayer cations. Reduction of M0S2 in DME electrolytes yields similar products. Basal spacings are dependant on solvent type and on ionic radius of A+. Further reduction of these compounds is associated with irreversible processes.
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